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The word "南京路" is formed by first combining the character 南, meaning "south", with 京, meaning "capital", to create the place name 南京 (Nanjing, historically "southern capital"), and then appending the character 路, meaning "road", to form a compound specifying a road named after that city.

Word Definition - 南京路

nán jīng lù Nanjing St., large commercial street in Shanghai