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The word 大腿袜 is formed by combining the characters 大 (big), 腿 (leg), and 袜 (sock); 大腿 together means "thigh", and adding 袜 specifies a type of sock that covers the thigh, resulting in the meaning "thigh-high sock".

Word Definition - 大腿袜

dà tuǐ wà thigh highs