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The word 水汪汪 is formed by using the character 水, meaning "water", as the semantic base to convey a watery quality, followed by the reduplication of the character 汪, which here acts as a descriptive suffix that emphasizes a state of being full or glistening with water, resulting in an adjective that depicts something as notably watery, such as teary or shimmering eyes.

Word Definition - 水汪汪

shuǐ wāng wāng watery; waterlogged (soil); limpid; bright and intelligent (eyes)