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"脱口而出" is formed by the direct sequential combination of the characters 脱 (meaning to slip off or shed), 口 (meaning mouth), 而 (a connective particle indicating sequence), and 出 (meaning to exit or come out), which together literally depict words slipping off the mouth and emerging, thus conveying the meaning of speaking impulsively without forethought.

Word Definition - 脱口而出

tuō kǒu ér chū (idiom) to blurt out; to let slip (an indiscreet remark)