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The word "孤苦伶仃" is formed by combining the two-character phrases "孤苦" and "伶仃", where "孤" means alone, "苦" means bitter or suffering, "伶" and "仃" together convey solitude and helplessness, resulting in a compound that intensifies the depiction of extreme loneliness and hardship through synonymous reinforcement.

Word Definition - 孤苦伶仃

gū kǔ líng dīng solitary and impoverished (idiom)