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The word "渺无人烟" is formed by sequentially combining the character 渺, meaning vast or indistinct, with 无, meaning without, and then the compound 人烟, where 人 means person and 烟 means smoke (here referring to signs of human life). This construction directly yields a literal sense of "vast and without human smoke", used to denote a place that is utterly desolate and uninhabited.

Word Definition - 渺无人烟

miǎo wú rén yān remote and uninhabited (idiom); deserted; God-forsaken