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The word "不择手段" is formed from the characters 不 (not), 择 (choose), and 手段 (means/methods), where 手 (hand) and 段 (segment) combine to signify "methods"; the literal sequence "not choose methods" yields the meaning of being willing to use any means, often unscrupulously, to achieve an end.

Word Definition - 不择手段

bù zé shǒu duàn by fair means or foul; by hook or by crook; unscrupulously