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The word 对阵 is formed by combining the character 对, meaning "to face" or "to oppose", with 阵, meaning "battle array" or "formation"; their conjunction literally denotes facing an opposing formation, which semantically extends to refer to direct confrontation between opponents in contexts like sports or conflicts.

Word Definition - 对阵

duì zhèn (of armies) to face each other, ready for battle; (sports) (of two teams) to play against each other

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