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The word 呲牙咧嘴 is formed by combining the two actions 呲牙 (baring teeth) and 咧嘴 (grinning widely), where means to expose, means teeth, means to stretch open, and means mouth; together, they literally describe the simultaneous act of showing teeth and opening the mouth wide, typically depicting a grimace or snarl.

Word Definition - 呲牙咧嘴

zī yá liě zuǐ to grimace (in pain); to show one's teeth; to bare one's fangs