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The word 受宠若惊 is formed by sequentially combining the characters (to receive), (favor), (as if), and (startled). The first two characters 受宠 create the concept of "receiving favor", which is then directly compared by 若惊 to the state of being "as if startled", resulting in a literal meaning of "receiving favor as if startled" to express the reaction to unexpected kindness.

Word Definition - 受宠若惊

shòu chǒng ruò jīng overwhelmed by favor from superior (humble expr.); to feel flattered and nervous