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The word "六十四卦" is formed by sequentially combining the characters for the numbers six ("六"), ten ("十"), and four ("四") to denote the quantity sixty-four, which directly modifies the character for divinatory hexagram ("卦"), resulting in a compound term that literally means "sixty-four hexagrams".

Word Definition - 六十四卦

liù shí sì guà the 64 hexagrams of the Book of Changes (I Ching or Yi Jing) 易經|易经