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The word 不假思索 is formed by combining the characters (not), (to borrow or rely on), (to think), and (to search), where 思索 together means "to think deeply". The sequence directly negates reliance on thought with modifying , which then applies to 思索, resulting in the literal meaning of "not relying on thinking and searching" to convey acting without hesitation or spontaneous action.

Word Definition - 不假思索

bù jiǎ sī suǒ to act without taking time to think (idiom); to react instantly; to fire from the hip